In recent years, large language models (LLMs) have driven major advances in language understanding, marking a significant step toward artificial general intelligence (AGI). With increasing demands for higher-level semantics and cross-modal fusion, multimodal large language models (MLLMs) have emerged, integrating diverse information sources (e.g., text, vision, and audio) to enhance modeling and reasoning in complex scenarios. In AI for Science, multimodal emotion recognition and reasoning has become a rapidly growing frontier. While LLMs and MLLMs have achieved notable progress in this area, the field still lacks a systematic review that consolidates recent developments. To address this gap, this paper provides a comprehensive survey of LLMs and MLLMs for emotion recognition and reasoning, covering model architectures, datasets, and performance benchmarks. We further highlight key challenges and outline future research directions, aiming to offer researchers both an authoritative reference and practical insights for advancing this domain. To the best of our knowledge, this paper is the first attempt to comprehensively survey the intersection of MLLMs with multimodal emotion recognition and reasoning. The summary of existing methods mentioned is in our Github: \href{https://github.com/yuntaoshou/Awesome-Emotion-Reasoning}{https://github.com/yuntaoshou/Awesome-Emotion-Reasoning}.

Accurate emotion perception is crucial for various applications, including human-computer interaction, education, and counseling.However, traditional single-modality approaches often fail to capture the complexity of real-world emotional expressions, which are inherently multimodal. To address this, we introduce the MERR dataset, containing 28,618 coarse-grained and 4,487 fine-grained annotated samples across diverse emotional categories. This dataset enables models to learn from varied scenarios and generalize to real-world applications. Furthermore, we propose Emotion-LLaMA, a model that seamlessly integrates audio, visual, and textual inputs through emotion-specific encoders. By aligning features into a shared space and employing a modified LLaMA model with instruction tuning, Emotion-LLaMA significantly enhances both emotional recognition and reasoning capabilities.